Yes, the rock5b work just fine. I also installed the UEFI into the SPI there (I have 2 Rock 5b) - I might want to give the itx a shot installing the UEFI into the SPI one day. There is something in the UEFI image which does not boot from SD; trying to find any docu about that - I came across one article mentioning some HW hack to change the boot order (probably what you described up there). The 5b and itx are quite different (itx is also 10-20% faster with higher clocks and faster RAM) but otherwise once the UEFI is installed, mine run the same OS. Unfortunately to run ACPI one needs a latest OS (Ubuntu 25 or Fedora Rawhide) - I haven't actually tried the mainline Armbian - I run KDE Plasma and while there was a Neon image somewhere most Armbian prebuilts don't run KDE (everytime I post install that, something else breaks).
Anyway, I am happy that everything is working now on all my Rock5 boards.