yes red are UART
please use 3,3V on you ch341 adapter
rx tx should be cross --> , tx form usb to rx from board , and rx from usb to tx from board , GND to GND
you can not break anything with change of Baud rate , try both and you are fine
the text that run automaticlly on UART is the serial log ,
when nothing or only some unreadable thing is show in putty please change baudrate
than copy the text from putty or other tool and post here for jock ,
also ANdroid will produce a log on UART ( with some diffirence)
many of this serial log also in android terminal demsg log
i dont know the usb port order , for multitool over USB the port is normally irrelevant ,some box need normal USB , some the USB otg , some box hasnt the usb otg